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Oxygen reduction catalyzed by a water-soluble binuclear copper(ii) complex from a neutral aqueous solution

Liu, Chengyu

Chemical communications. Volume 53:Issue 22 (2017); pp 3189-3192 -- Royal Society of Chemistry

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  • Title:
    Oxygen reduction catalyzed by a water-soluble binuclear copper(ii) complex from a neutral aqueous solution
  • Author: Liu, Chengyu;
    Lei, Haitao;
    Zhang, Zongyao;
    Chen, Fangfang;
    Cao, Rui
  • Found In: Chemical communications. Volume 53:Issue 22 (2017); pp 3189-3192
  • Journal Title: Chemical communications
  • Subjects: Chemistry--Periodicals; Dewey: 540
  • Rights: legaldeposit
  • Publication Details: Royal Society of Chemistry
  • Abstract: Abstract :

    A water-soluble binuclear Cu II complex of a polypyridine–polyamide ligand can catalyze oxygen reduction to water from neutral aqueous solutions.

    Abstract :

    A water-soluble binuclear Cu II complex, synthesized using a polypyridine–polyamide ligand, was able to catalyze oxygen reduction to water from neutral aqueous solutions. Electrocatalytic results suggested that one Cu II center was first reduced by one electron to form a Cu II Cu I species, which reacted with O2to give a superoxide radical intermediate.


  • Identifier: System Number: LDEAvdc_100045194134.0x000001; Journal ISSN: 1359-7345; 10.1039/c6cc09206c
  • Publication Date: 2017
  • Physical Description: Electronic
  • Shelfmark(s): ELD Digital store

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