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Poly[[chlorido(1, 10‐phenanthroline‐κ2N, N′)copper(II)]‐μ3‐1, 1, 3, 3‐tetracyano‐2‐ethoxypropenido‐κ3N:N′:N′′]: coordination polymer sheets linked into bilayers by hydrogen bonds

Setifi, Zouaoui et al.

Acta crystallographica. Section C. Structural chemistry. Volume 70:Issue 1 (2014, January); pp 19-22 -- John Wiley & Sons Ltd

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  • Title:
    Poly[[chlorido(1, 10‐phenanthroline‐κ2N, N′)copper(II)]‐μ3‐1, 1, 3, 3‐tetracyano‐2‐ethoxypropenido‐κ3N:N′:N′′]: coordination polymer sheets linked into bilayers by hydrogen bonds
  • Author: Setifi, Zouaoui;
    Setifi, Fatima;
    El Ammari, Lahcen;
    El‐Ghozzi, Malika;
    Sopková‐de Oliveira Santos, Jana;
    Merazig, Hocine;
    Glidewell, Christopher
  • Found In: Acta crystallographica. Section C. Structural chemistry. Volume 70:Issue 1 (2014, January); pp 19-22
  • Journal Title: Acta crystallographica. Section C. Structural chemistry
  • Subjects: Crystallography--Periodicals; Crystals--Periodicals; Dewey: 548.3
  • Rights: legaldeposit
  • Publication Details: John Wiley & Sons Ltd
  • Abstract: <x xml:space="preserve">Abstract</x>

    In the title compound, [Cu(C9H5N4O)Cl(C12H8N2)]n or [Cu(tcnoet)Cl(phen)]n, where phen is 1, 10‐phenanthroline and tcnoet is 1, 1, 3, 3‐tetracyano‐2‐ethoxypropenide, the axially elongated (4 + 2) coordination polyhedron around the CuII centre contains N atoms from three different tcnoet ligands. The resulting coordination polymer takes the form of sheets which are linked in pairs by a single C—H...N hydrogen bond to form bilayers. The bond lengths provide evidence for significant bond fixation in the phen ligand and extensive electronic delocalization in the tcnoet ligand, where the two –C(CN)2 units are rotated, in conrotatory fashion, out of the plane of the central C3O fragment.


  • Identifier: ETOClsidyv8a366580; System Number: LDEAvdc_100024837351.0x000001; Journal ISSN: 2053-2296; 10.1107/S2053229613032804
  • Publication Date: 2014
  • Physical Description: Electronic
  • Shelfmark(s): ELD Digital store

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