skip to main content
Show Results with:

SrCl2 as an efficient cocatalyst for acidic hydrolysis of methyl glycosides

Shi, Yong-Heng et al.

Chinese chemical letters: Zhongguo hua xue kuai bao. Volume 25:Number 4(2014); 201404; 561-566 -- Elsevier B.V.

Online access

  • Title:
    SrCl2 as an efficient cocatalyst for acidic hydrolysis of methyl glycosides
  • Author: Shi, Yong-Heng;
    Xie, Ya-Fei;
    Liu, Yu-Qiang;
    Wei, Qun-Chao;
    Xu, Wei-Ren;
    Tang, Li-Da;
    Zhao, Gui-Long
  • Found In: Chinese chemical letters: Zhongguo hua xue kuai bao. Volume 25:Number 4(2014); 201404; 561-566
  • Journal Title: Chinese chemical letters: Zhongguo hua xue kuai bao
  • Subjects: Chemistry; Chimie; LCSH: Chemistry; Dewey: 540.5
  • Rights: Licensed
  • Publication Details: Elsevier B.V.
  • Abstract: Graphical abstractSrCl2was found to be the most efficient cocatalyst for the acidic hydrolysis of methyl glycosides among 26 metal salts screened as Lewis acid. The SrCl2-cocatalyzed acidic hydrolysis of methyl glycosides was highlighted by short reaction times, less byproducts and high yields, and was applicable to a variety of methyl glycosides, especially to those withO-benzyl protecting groups.AbstractSrCl2was found to be the most efficient cocatalyst for the acidic hydrolysis of methyl glycosides after 26 kinds of most representative metal salts were screened. The SrCl2-cocatalyzed acidic hydrolysis of methyl glycosides is highlighted by short reaction times, less byproducts and high yields. A possible mechanism for the SrCl2-cocatalyzed hydrolysis is also proposed.
  • Identifier: Journal ISSN: 1001-8417
  • Publication Date: 2014
  • Physical Description: Electronic
  • Shelfmark(s): 3180.274300
  • UIN: ETOCvdc_100057030520.0x000001

Searching Remote Databases, Please Wait