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Reactions of Tertiary Allylic Amines and Dichlorocarbenes

Wang, Meili et al.

Synthetic communications -- Taylor & Francis Group -- Volume: 45 19; (pages 2259-2265) -- 2015

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  • Title:
    Reactions of Tertiary Allylic Amines and Dichlorocarbenes
  • Author: Wang, Meili;
    Xiao, Fenfen;
    Bai, Yinjuan;
    Hu, Xiangdong
  • Found In: Synthetic communications. Volume 45:Number 19(2015); 20151002; 2259-2265
  • Journal Title: Synthetic communications
  • Subjects: Organic compounds Synthesis; Chemistry, Organic; Synthesis; LCSH: Organic compounds Synthesis; Dewey: 547.205
  • Rights: Licensed
  • Publication Details: Taylor & Francis Group
  • Abstract: Abstract

    In this article, a study on reactions of tertiary allylic amines and dichlorocarbenes had been described. Tertiary allylic amines could result from an interesting de-N-allylation/formylation reaction under the treatment of dichlorocarbenes. Notably, amines containing steric substituents or electron-deficient aromatic substituents on the nitrogen will go through cyclopropanations of the carbon–carbon double bond.

    GRAPHICAL ABSTRACT

  • Identifier: Journal ISSN: 0039-7911
  • Publication Date: 2015
  • Physical Description: Electronic
  • Shelfmark(s): ELD Digital store
    8586.830000
  • UIN: ETOCvdc_100032654489.0x000001

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