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Magnetic properties of ternary chromium sulfides, V~xCr~3~-~xS~4 (0 ó x ó 1.0)

Powell, A. V.; Oestreich, S.

Journal of materials chemistry. VOL 6; NUMBER 5, ; 1996, 807-814 -- ROYAL SOCIETY OF CHEMISTRY Part: Part 5; (pages 807-814) -- 1996

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  • Title:
    Magnetic properties of ternary chromium sulfides, V~xCr~3~-~xS~4 (0 ó x ó 1.0)
  • Author: Powell, A. V.;
    Oestreich, S.
  • Found In: Journal of materials chemistry. VOL 6; NUMBER 5, ; 1996, 807-814
  • Journal Title: Journal of materials chemistry.
  • Subjects: Electrical and Electronic Engineering; Mechanical Engineering; Civil Engineering; Biotechnology; Chemistry; Pharmaceutical Chemistry; Dewey: 540 620
  • Publication Details: ROYAL SOCIETY OF CHEMISTRY
  • Language: English
  • Abstract: A series of phases V~xCr~3~-~xS~4 (0.0 ó x ó 1.0) have been prepared by high-temperature synthesis and characterised by thermogravimetry, energy dispersive X-ray microanalysis and powder X-ray diffraction in conjunction with Rietveld profile analysis. Data are consistent with the formation of single-phase products which all adopt the Cr~3S~4 structure (space group 12/m: a approximately equal to 5.9, b approximately equal to 3.4, c approximately equal to 11.2 ?, á approximately equal to 91.4ø). Magnetic susceptibility data indicate that spin-glass behaviour persists in the range 0.4 ó x ó 1.0, whilst data for x = 0.2 suggest that there is a slow freezing of spins prior to the onset of long-range magnetic ordering observed for x = 0.0.
  • Identifier: Journal ISSN: 0959-9428
  • Publication Date: 1996
  • Physical Description: Physical
  • Accrual Information: Monthly
  • Shelfmark(s): 5012.205000
  • UIN: ETOCRN007778983

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